Hamad Bin Khalifa University
Click on New Group on the left menu in Mendeley and Name your group. The invitees are not required to have a Mendeley library to receive an invitation but they will be prompted to create an account.

When someone invites you to join a Mendeley group, you receive an email notification.
Click on the Join this group link in the email; you will be redirected to the Mendeley website. 
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